Iron-catalyzed decarboxylative radical addition to chiral azomethine imines upon visible light

被引：7

作者：

Fall, Arona ^{[1
]}

Magdei, Mihaela ^{[1
]}

Savchuk, Mariia ^{[1
]}

Oudeyer, Sylvain ^{[1
]}

Beucher, Helene ^{[1
]}

Briere, Jean-Francois ^{[1
]}

机构：

[1] Univ Rouen Normandie, Normandie Univ, INSA Rouen Normandie, CNRS,UMR 6014,INC3M FR 3038, F-76000 Rouen, France

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 49期

关键词：

CHARGE-TRANSFER;

D O I：

10.1039/d4cc01766h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we disclose an eco-efficient redox-neutral iron-catalyzed decarboxylative radical addition to chiral azomethine imines upon visible light (427 nm) giving cyclic hydrazine derivatives with dr ranging from 82 : 18 to >96 : 4. This earth-abundant metal promoted sequence proceeds efficiently under ligand-free conditions based on a LMCT process and opens a route to new chiral heterocycles.

引用

页码：6316 / 6319

页数：4

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