Iron-catalyzed decarboxylative radical addition to chiral azomethine imines upon visible light

被引：7
|
作者：
Fall, Arona [1 ]
Magdei, Mihaela [1 ]
Savchuk, Mariia [1 ]
Oudeyer, Sylvain [1 ]
Beucher, Helene [1 ]
Briere, Jean-Francois [1 ]
机构：
[1] Univ Rouen Normandie, Normandie Univ, INSA Rouen Normandie, CNRS,UMR 6014,INC3M FR 3038, F-76000 Rouen, France
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 49期
关键词：
CHARGE-TRANSFER;
D O I：
10.1039/d4cc01766h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Herein, we disclose an eco-efficient redox-neutral iron-catalyzed decarboxylative radical addition to chiral azomethine imines upon visible light (427 nm) giving cyclic hydrazine derivatives with dr ranging from 82 : 18 to >96 : 4. This earth-abundant metal promoted sequence proceeds efficiently under ligand-free conditions based on a LMCT process and opens a route to new chiral heterocycles.
引用
收藏
页码：6316 / 6319
页数：4
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