Crystal structure of (E)-2-[(2S,5R)-2isopropyl-5-methylcyclohexylidene]hydrazine-1-carbothioamide

被引：0

作者：

de Oliveira, Adriano Bof ^{[1
]}

Beck, Johannes ^{[2
]}

Daniels, Joerg ^{[2
]}

de Farias, Renan Lira ^{[1
]}

de Godoy Netto, Adelino Vieira ^{[3
]}

机构：

[1] Univ Fed Sergipe, Dept Quim, Av Marechal Rondon S-N,Campus, BR-49100000 Sao Cristovao, SE, Brazil

[2] Univ Bonn, Inst Anorgan Chem, D-53121 Bonn, Germany

[3] Univ Estadual Paulista, Inst Quim, BR-14801970 Araraquara, SP, Brazil

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

thiocarbazone; hydrogen-bonding polymer; crystal structure;

D O I：

10.1107/S1600536814015980

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C11H21N3S, consists of a menthone moiety attached to an extended thiosemicarbazone group with the N-N-C-N torsion angle being 11.92 (16)degrees. The cyclohexane ring has a chair conformation and the conformation about the C = N bond is E. In the crystal, molecules are linked via pairs of N-H center dot center dot center dot S hydrogen bonds, forming chains along the a axis. The absolute structure could be assigned with reference to the starting material, i.e. enantiopure (-)-menthone [Flack parameter = 0.05 (5)].

引用

页码：O903 / +

页数：8

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