Crystal structure of (E)-2-[(2S,5R)-2isopropyl-5-methylcyclohexylidene]hydrazine-1-carbothioamide

被引：0
|
作者：
de Oliveira, Adriano Bof [1 ]
Beck, Johannes [2 ]
Daniels, Joerg [2 ]
de Farias, Renan Lira [1 ]
de Godoy Netto, Adelino Vieira [3 ]
机构：
[1] Univ Fed Sergipe, Dept Quim, Av Marechal Rondon S-N,Campus, BR-49100000 Sao Cristovao, SE, Brazil
[2] Univ Bonn, Inst Anorgan Chem, D-53121 Bonn, Germany
[3] Univ Estadual Paulista, Inst Quim, BR-14801970 Araraquara, SP, Brazil
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
thiocarbazone; hydrogen-bonding polymer; crystal structure;
D O I：
10.1107/S1600536814015980
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, C11H21N3S, consists of a menthone moiety attached to an extended thiosemicarbazone group with the N-N-C-N torsion angle being 11.92 (16)degrees. The cyclohexane ring has a chair conformation and the conformation about the C = N bond is E. In the crystal, molecules are linked via pairs of N-H center dot center dot center dot S hydrogen bonds, forming chains along the a axis. The absolute structure could be assigned with reference to the starting material, i.e. enantiopure (-)-menthone [Flack parameter = 0.05 (5)].
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收藏
页码：O903 / +
页数：8
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