A HORNER-WADSWORTH-EMMONS APPROACH TO [(S)R]-4-SUBSTITUTED 1-P-TOLYLSULFINYL-1,3-DIENES

被引：16

作者：

ARCE, E

CARRENO, MC

CID, MB

RUANO, JLG

机构：

[1] Departamento de Química Orgánica (C-I), Universidad Autónoma, Cantoblanco

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 07期

关键词：

D O I：

10.1016/0957-4166(95)00221-A

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[(S)R,1E,3E]-4-p-Tolylsulfinyl-1-X-1,3-butadienes 1 (X = CO(2)Me, CN, PO(OEt)(2), SO2 Ph, SEt) are synthesized from a common starting material, [(S)R]-3-p-tolylsulfinyl-2-propenal 2, through a Horner-Wadsworth-Emmons reaction with the phosphonate (XCH(2)PO(OEt)(2)). The synthesis of 2 is also described.

引用

页码：1757 / 1764

页数：8

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