A HORNER-WADSWORTH-EMMONS APPROACH TO [(S)R]-4-SUBSTITUTED 1-P-TOLYLSULFINYL-1,3-DIENES

被引：16
|
作者：
ARCE, E
CARRENO, MC
CID, MB
RUANO, JLG
机构：
[1] Departamento de Química Orgánica (C-I), Universidad Autónoma, Cantoblanco
来源：
TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 07期
关键词：
D O I：
10.1016/0957-4166(95)00221-A
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[(S)R,1E,3E]-4-p-Tolylsulfinyl-1-X-1,3-butadienes 1 (X = CO(2)Me, CN, PO(OEt)(2), SO2 Ph, SEt) are synthesized from a common starting material, [(S)R]-3-p-tolylsulfinyl-2-propenal 2, through a Horner-Wadsworth-Emmons reaction with the phosphonate (XCH(2)PO(OEt)(2)). The synthesis of 2 is also described.
引用
收藏
页码：1757 / 1764
页数：8
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