ENANTIOSELECTIVE SYNTHESIS OF (-)-DESOXOPROSOPININE BY RADICAL CYCLIZATION

被引：20

作者：

YUASA, Y ^{[1
]}

ANDO, J ^{[1
]}

SHIBUYA, S ^{[1
]}

机构：

[1] TOKYO UNIV PHARM & LIFE SCI,SCH PHARM,HACHIOJI,TOKYO 19203,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 07期

关键词：

D O I：

10.1016/0957-4166(95)00189-V

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the aldehyde 12 with tributyltin hydride in the presence of AIBN gave a mixture of 13 as a 2:1 mixture of 8 beta-ol. and 8 alpha-ol. Conversion of 14, derived from 13, to (-)-desoxoprosopinine 3 was successfully achieved.

引用

页码：1525 / 1526

页数：2

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