ENANTIOSELECTIVE SYNTHESIS OF (-)-DESOXOPROSOPININE BY RADICAL CYCLIZATION

被引：20
|
作者：
YUASA, Y [1 ]
ANDO, J [1 ]
SHIBUYA, S [1 ]
机构：
[1] TOKYO UNIV PHARM & LIFE SCI,SCH PHARM,HACHIOJI,TOKYO 19203,JAPAN
来源：
TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 07期
关键词：
D O I：
10.1016/0957-4166(95)00189-V
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of the aldehyde 12 with tributyltin hydride in the presence of AIBN gave a mixture of 13 as a 2:1 mixture of 8 beta-ol. and 8 alpha-ol. Conversion of 14, derived from 13, to (-)-desoxoprosopinine 3 was successfully achieved.
引用
收藏
页码：1525 / 1526
页数：2
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