SENSITIVE AND INSENSITIVE REACTIONS ON COPPER CATALYSTS: THE WATER-GAS SHIFT REACTION AND METHANOL SYNTHESIS PROM CARBON DIOXIDE

被引：79

作者：

Chinchen, G. C. ^{[1
]}

Spencer, M. S. ^{[2
]}

机构：

[1] ICI Chem & Polymers Ltd, Catalysis Res Ctr, Billingham TS23 1LB, Cleveland, England

[2] Univ Wales, Coll Cardiff, Sch Chem & Appl Chem, Cardiff CF1 3TB, S Glam, Wales

来源：

CATALYSIS TODAY | 1991年 / 10卷 / 03期

关键词：

D O I：

10.1016/0920-5861(91)80009-X

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The catalytic activity and in situ copper metal areas have been determined for series of Cu/ZnO/Al(2)O(3) catalysts in methanol synthesis from carbon dioxide and in the water-gas shift reaction. Methanol synthesis is an insensitive catalytic reaction, in agreement with our and other previous studies, whereas the water-gas shift reaction is sensitive to catalyst parameters other than copper metal area. This contrast is interpreted in terms of the unified reaction mechanism proposed before.

引用

页码：293 / 301

页数：9

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