SENSITIVE AND INSENSITIVE REACTIONS ON COPPER CATALYSTS: THE WATER-GAS SHIFT REACTION AND METHANOL SYNTHESIS PROM CARBON DIOXIDE

被引：79
|
作者：
Chinchen, G. C. [1 ]
Spencer, M. S. [2 ]
机构：
[1] ICI Chem & Polymers Ltd, Catalysis Res Ctr, Billingham TS23 1LB, Cleveland, England
[2] Univ Wales, Coll Cardiff, Sch Chem & Appl Chem, Cardiff CF1 3TB, S Glam, Wales
来源：
CATALYSIS TODAY | 1991年 / 10卷 / 03期
关键词：
D O I：
10.1016/0920-5861(91)80009-X
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The catalytic activity and in situ copper metal areas have been determined for series of Cu/ZnO/Al(2)O(3) catalysts in methanol synthesis from carbon dioxide and in the water-gas shift reaction. Methanol synthesis is an insensitive catalytic reaction, in agreement with our and other previous studies, whereas the water-gas shift reaction is sensitive to catalyst parameters other than copper metal area. This contrast is interpreted in terms of the unified reaction mechanism proposed before.
引用
收藏
页码：293 / 301
页数：9
相关论文
共 50 条
  • [21] Development of high performance Cu/ZnO-based catalysts for methanol synthesis and the water-gas shift reaction
    Saito, M
    Murata, K
    CATALYSIS SURVEYS FROM ASIA, 2004, 8 (04) : 285 - 294
  • [22] Development of high performance Cu/ZnO-based catalysts for methanol synthesis and the water-gas shift reaction
    Masahiro Saito
    Kazuhisa Murata
    Catalysis Surveys from Asia, 2004, 8 : 285 - 294
  • [23] EFFECT OF THE WATER-GAS REACTION ON THE METHANOL SYNTHESIS
    ARVA, P
    SZEIFERT, F
    CHEMICAL ENGINEERING COMMUNICATIONS, 1989, 76 : 195 - 206
  • [24] WATER-GAS SHIFT REACTION - A COMPARISON OF INDUSTRIAL CATALYSTS
    GOODRIDGE, F
    QUAZI, HA
    TRANSACTIONS OF THE INSTITUTION OF CHEMICAL ENGINEERS AND THE CHEMICAL ENGINEER, 1967, 45 (07): : T274 - +
  • [25] Rational design of catalysts for water-gas shift reaction
    Fox, Joshua
    Dinescu, Adriana
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [26] Importance of the metal-oxide interface in catalysts for the water-gas shift and methanol synthesis
    Rodriguez, Jose
    Stacchiola, Dario
    Liu, Ping
    Senanayake, Sanjaya
    Graciani, Jesus
    Sanz, Javier
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [27] In situ infrared study of formate reactivity on water-gas shift and methanol synthesis catalysts
    Kobl, Kilian
    Angelo, Laetitia
    Zimmermann, Yvan
    Sall, Secou
    Parkhomenko, Ksenia
    Roger, Anne-Cecile
    COMPTES RENDUS CHIMIE, 2015, 18 (03) : 302 - 314
  • [28] Kinetics of the water-gas shift reaction over nanostructured copper-ceria catalysts
    Kusar, H
    Hocevar, S
    Levec, J
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 63 (3-4) : 194 - 200
  • [29] METHANOL SYNTHESIS AND REVERSE WATER-GAS SHIFT KINETICS OVER CLEAN POLYCRYSTALLINE COPPER
    YOSHIHARA, J
    PARKER, SC
    SCHAFER, A
    CAMPBELL, CT
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 209 : 207 - COLL
  • [30] METHANOL SYNTHESIS AND REVERSE WATER-GAS SHIFT KINETICS OVER CLEAN POLYCRYSTALLINE COPPER
    YOSHIHARA, J
    PARKER, SC
    SCHAFER, A
    CAMPBELL, CT
    CATALYSIS LETTERS, 1995, 31 (04) : 313 - 324
12345