THERMODYNAMIC INVESTIGATION OF THE SORPTION OF FE-3(+) AND CU-2(+) IONS BY A FIBROUS POLYAMPHOLYTE

被引：1
|
作者：
TERLEMEZIAN, E
VELEVA, S
ARSOV, A
机构：
[1] Institute of Chemical Technology, Sofia
来源：
ACTA POLYMERICA | 1990年 / 41卷 / 01期
关键词：
D O I：
10.1002/actp.1990.010410110
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The sorption of Fe3+ and Cu2+ ions on a fibrous polyampholyte synthesized by modification of PAN fibres with EDA is studied by thermodynamic methods. The endothermic adsorption process and the positive change of the entropy of the system with the established effect of compensation between ΔH and ΔS are an indication for the complicated mechanism of the chemisorption with complex formation. The complexes formed with the both ions are different. The pH value of the metal salt solutions affect strongly on the adsorption process. At pH > 2 sorption of Cu2+ dominates, while at lower pH values sorption of Fe3+ prevails. © 1990 Akademie Verlag GmbH, Berlin
引用
收藏
页码：42 / 45
页数：4
相关论文
共 50 条
  • [31] EXPERIMENTS ON THE SPUTTERING OF NEUTRAL CU-2 DIMERS FROM CU BY AR+ IONS (60-300 EV)
    COOPER, CB
    HAMED, HA
    SURFACE SCIENCE, 1984, 143 (01) : 215 - 222
  • [32] Kinetics and Equilibrium Sorption of Cation Cu2+ by Polyampholyte Hydrogels Based on Hydrolyzed Polyacrylamide and Aliphatic Diamines
    V. A. Lipin
    A. N. Evdokimov
    T. A. Sustavova
    Yu. A. Petrova
    Russian Journal of Physical Chemistry A, 2022, 96 : 645 - 647
  • [33] REACTION OF SYNTHETIC STYRENE POLYAMPHOLYTE-COPOLYMER AND N,N-DIMETHYLAMINOPROPYLMONOAMIDE OF MALEIC-ACID, WITH CU2+ AND FE3+ IONS IN AQUEOUS-SOLUTION
    BEKTUROV, EA
    KUDAIBERGENOV, SE
    ZHAIMINA, GM
    KOORDINATSIONNAYA KHIMIYA, 1984, 10 (07): : 942 - 946
  • [34] SYNTHESIS AND REACTIVITY OF [FE-3(CO)(9)TE](2-)
    ROOF, LC
    SMITH, DM
    DRAKE, GW
    PENNINGTON, WT
    KOLIS, JW
    INORGANIC CHEMISTRY, 1995, 34 (01) : 337 - 345
  • [35] Crystal structure of clinoatacamite, a new polymorph of Cu-2(OH)(3)Cl
    Grice, JD
    Szymanski, JT
    Jambor, JL
    CANADIAN MINERALOGIST, 1996, 34 : 73 - 78
  • [36] Effects of metal ions (Cu2+, Fe2+ and Fe3+) on HPLC analysis of catechins
    Yasuda, Midori
    Matsuda, Chika
    Ohshiro, Ayumi
    Inouye, Kuniyo
    Tabata, Masaaki
    FOOD CHEMISTRY, 2012, 133 (02) : 518 - 525
  • [37] KINETICS OF FE-2(+) OXIDATION AND FE-3(+) REDUCTION IN MGO SINGLE-CRYSTALS
    SONDER, E
    STRATTON, TG
    WEEKS, RA
    JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (10): : 4603 - 4608
  • [38] Investigation by the thermodynamic simulation methods of the Cu-O system with the use of thermodynamic functions for condensed Cu2O3, Cu4O3, Cu3O2, CuO and Cu2O
    Moiseev, GK
    Vatolin, NA
    DOKLADY AKADEMII NAUK, 1997, 356 (02) : 205 - 207
  • [39] Thermodynamic assessment of the CaO-Cu2O-FeO-Fe2O3 system
    Shishin, Denis
    Hidayat, Taufiq
    Jak, Evgueni
    CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2020, 68 (68):
  • [40] Sorption of co(ii) ions onto mechanically activated γ-Fe2O3 powders
    1600, Izdatel'stvo Nauka (87):
12345