STRUCTURE OF 3,5-DI-TERT-BUTYL-10-IODOPROTOADAMANTANE

被引：1
|
作者：
KOJICPRODIC, B [1 ]
LUIC, M [1 ]
NIGOVIC, B [1 ]
DUDDECK, H [1 ]
ROSENBAUM, D [1 ]
机构：
[1] RUHR UNIV BOCHUM, FAK CHEM, W-4630 BOCHUM, GERMANY
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1992年 / 48卷
关键词：
D O I：
10.1107/S0108270191007758
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
6,7a-Di-tert-butyl-8-iodooctahydro-2,5-methano-1 H-indene, C18H31I, M(r) = 374.35, monoclinic, P2(1), a = 9.095 (1), b = 7.087 (1), c = 14.149 (2) angstrom, beta = 107.87 (3)-degrees, V = 867.9 (2) angstrom 3, Z = 2, D(x) = 1.432 g cm-3, lambda(Mo K-alpha) = 0.71073 angstrom, mu = 18.1 cm-1, F(000) = 384, T = 293 K, R = 0.025 for 1673 observed reflections [F0 greater-than-or-equal-to 4-sigma(F0)]. The protoadamantane cage has a five-membered ring in the envelope conformation, one six-membered ring (with the I substituent) in a distorted chair conformation and the other six-membered ring (with two tert-butyl groups) in a boat conformation. The I atom is in an axial position. Molecules are joined by van der Waals contacts.
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页码：131 / 133
页数：3
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