ELECTROCHEMICAL SYNTHESIS OF PYRIDINE-2-THIONATO COMPLEXES OF ZINC(II) AND CADMIUM(II) - THE CRYSTAL-STRUCTURE OF 1,10-PHENANTHROLINE-BIS(PYRIDINE-2-THIONATO)ZINC(II)

被引：43

作者：

DURAN, ML ^{[1
]}

ROMERO, J ^{[1
]}

GARCIAVAZQUEZ, JA ^{[1
]}

CASTRO, R ^{[1
]}

CASTINEIRAS, A ^{[1
]}

SOUSA, A ^{[1
]}

机构：

[1] UNIV SANTIAGO DE COMPOSTELA,DEPT QUIM INORGAN,SANTIAGO,SPAIN

来源：

POLYHEDRON | 1991年 / 10卷 / 02期

关键词：

D O I：

10.1016/S0277-5387(00)81589-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Zinc and cadmium pyridine-2-thionato complexes, M(pyt)2, were prepared by direct electrochemical oxidation of the metal into a solution of pyridine-2-thione (pytH) in acetonitrile. Adducts of type [M(pyt)2L] (L = 2,2'-bipyridine or 1,10-phenanthroline) were obtained by addition of the ligand to the electrolyte phase. X-ray structure determination of [Zn(pyt)2phen] shows the molecule to have a distorted octahedral trans-ZnS2N4 core, with average bond distances of 2.182 angstrom for Zn-N(phen), 2.061 angstrom for Zn-N(pyt) and 2.586 angstrom for Zn-S. The vibrational, H-1 and C-13 NMR spectra of the compounds are discussed.

引用

页码：197 / 202

页数：6

共 50 条

[21] NEW FLUXIONAL 7-CO-ORDINATE MOLYBDENUM(II) AND TUNGSTEN(II) COMPLEXES - X-RAY STRUCTURE OF THE PYRIDINE-2-THIONATO COMPLEX [W(C5H4NS)2(CO)2(PME2PH)]
DEEMING, AJ
KARIM, M
POWELL, NI
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (08): : 2321 - 2324
[22] REDOX PROPERTIES OF BIS(1,10-PHENANTHROLINE)-(PYRIDINE)RUTHENIUM(II) COMPLEXES
LAWRANCE, GA
POLYHEDRON, 1985, 4 (05) : 817 - 820
[23] Electrochemical synthesis and crystal structure of cobalt(II), nickel(II), copper(II), zinc(II) and cadmium(II) complexes with 2-pyridinecarbaldehyde-(2′-aminosulfonylbenzoyl)hydrazone
Sousa-Pedrares, Antonio
Camina, Nuria
Romero, Jaime
Duran, Maria L.
Garcia-Vazquez, Jose A.
Sousa, Antonio
POLYHEDRON, 2008, 27 (16) : 3391 - 3397
[24] Synthesis, Crystal Structure and Photoluminescence of Zinc(II) Complexes with a D-π-A Pyridine Ligand
Xu Yan
Li Wei-Jie
Wu Jie-Ying
Zhou Hong-Ping
Yang Jia-Xiang
Li Sheng-Li
Tian Yu-Peng
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2010, 26 (06) : 997 - 1002
[25] 6-COORDINATE COMPLEXES WITH 1,10-PHENANTHROLINE LIGANDS IN THE TRANS CONFIGURATION - PREPARATION OF TRANS-BIS(1,10-PHENANTHROLINE)RUTHENIUM(II) COMPLEXES AND CRYSTAL-STRUCTURE OF TRANS-BIS(1,10-PHENANTHROLINE)BIS(PYRIDINE)RUTHENIUM(II) HEXAFLUOROPHOSPHATE
BONNESON, P
WALSH, JL
PENNINGTON, WT
CORDES, AW
DURHAM, B
INORGANIC CHEMISTRY, 1983, 22 (12) : 1761 - 1765
[26] BIS(1,10-PHENANTHROLINE)COPPER(II) COMPLEXES - REFINEMENT OF THE CRYSTAL-STRUCTURE OF THE DITHIOCYANATO-BIS(1,10-PHENANTHROLINE)COPPER(II) COMPLEX
KABESOVA, M
KOZISKOVA, Z
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1992, 57 (06) : 1269 - 1277
[27] Synthesis, structure and luminescent properties of zinc(II) and Hg(II) complexes with substituted 1,10-phenanthroline
Liu, Xiaoming
Xia, Hong
Gao, Wei
Gao, Bo
Mu, Ying
JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (03) : 400 - 409
[28] CYANOACETATES OF MANGANESE(II), COBALT(II) AND ZINC(II) AND THEIR PYRIDINE AND 2,2'-BIPYRIDYL COMPLEXES
CARTWRIGHT, M
EDWARDS, DA
POTTS, JM
INORGANICA CHIMICA ACTA, 1979, 34 (02) : 211 - 220
[29] Copper(II), cobalt(II) and zinc(II) complexes based on a tridentate bis(benzimidazole)pyridine ligand: synthesis, crystal structures, electrochemical properties and antitumour activities
Rong-Kai Pan
Jiang-Li Song
Guo-Bi Li
San-Qing Lin
Sheng-Gui Liu
Gui-Zhen Yang
Transition Metal Chemistry, 2017, 42 : 253 - 262
[30] Synthesis, crystal structure and electrochemical behaviour of tris(1,10-phenanthroline)zinc(II) tetrametavanadate octahydrate
Xie, AL
Xu, DJ
Xu, YZ
Zhou, KJ
ACTA CHIMICA SINICA, 1997, 55 (09) : 853 - 859

← 1 2 3 4 5 →