DIVERGENT BEHAVIOR IN THE ISOCYANATE-INDUCED AND THERMAL GENERATION OF NITRILE OXIDES FROM ETHYL NITROACETATE

被引：15

作者：

LESLIESMITH, MG

PATON, RM

WEBB, N

机构：

[1] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

[2] CASTROL INT,CTR TECHNOL,READING RG8 7QR,BERKS,ENGLAND

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 49期

关键词：

D O I：

10.1016/0040-4039(94)88480-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ethyl nitroacetate is a source of three nitrile oxides: thermolysis results in elimination of ethanol and carbon dioxide to generate formonitrile oxide (HC=N+-O-), whereas treatment with phenyl isocyanate and a base gives either ethoxy-carbonylformonitrile oxide (EtO(2)CC=N+-O-) or cyanoformanilide N-oxide (PhNHCOC=N+-O-) depending on the reaction conditions.

引用

页码：9251 / 9254

页数：4

共 49 条

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