DIVERGENT BEHAVIOR IN THE ISOCYANATE-INDUCED AND THERMAL GENERATION OF NITRILE OXIDES FROM ETHYL NITROACETATE

被引：15
|
作者：
LESLIESMITH, MG
PATON, RM
WEBB, N
机构：
[1] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND
[2] CASTROL INT,CTR TECHNOL,READING RG8 7QR,BERKS,ENGLAND
来源：
TETRAHEDRON LETTERS | 1994年 / 35卷 / 49期
关键词：
D O I：
10.1016/0040-4039(94)88480-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Ethyl nitroacetate is a source of three nitrile oxides: thermolysis results in elimination of ethanol and carbon dioxide to generate formonitrile oxide (HC=N+-O-), whereas treatment with phenyl isocyanate and a base gives either ethoxy-carbonylformonitrile oxide (EtO(2)CC=N+-O-) or cyanoformanilide N-oxide (PhNHCOC=N+-O-) depending on the reaction conditions.
引用
收藏
页码：9251 / 9254
页数：4
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