POLYMER-SUPPORTED SOLUTION SYNTHESIS OF A HEPTAGLUCOSIDE HAVING PHYTOALEXIN ELICITOR ACTIVITY

被引：0
|
作者：
VERDUYN, R
VANDERKLEIN, PAM
DOUWES, M
VANDERMAREL, GA
VANBOOM, JH
机构：
来源：
RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY | 1993年 / 112卷 / 7-8期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient synthesis of methyl heptaglucoside 2 using poly(ethyleneglycol)monomethyl ether as a polymer support is described. Elongation of the acceptor 11, anchored via a succinoyl linkage to PEG, with the appropriate glycosyl donors 4-6 and intermittent protective group manipulations gave fully protected heptamer 18. Deprotection of 18 furnished, after purification as its peracetate, title compound 2 in a good overall yield.
引用
收藏
页码：464 / 466
页数：3
相关论文
共 50 条
  • [21] A practical process for polymer-supported synthesis
    Quiclet-Sire, B
    Wilczewska, A
    Zard, SZ
    TETRAHEDRON LETTERS, 2000, 41 (30) : 5673 - 5677
  • [22] Polymer-Supported Stereoselective Synthesis of Benzimidazolinopiperazinones
    Cankarova, Nadezda
    Krchnak, Viktor
    JOURNAL OF ORGANIC CHEMISTRY, 2012, 77 (13): : 5687 - 5695
  • [23] Soluble polymer-supported synthesis of arylpiperazines
    Pan, PC
    Sun, CM
    TETRAHEDRON LETTERS, 1998, 39 (51) : 9505 - 9508
  • [24] SYNTHESIS OF DITHIOESTERS WITH POLYMER-SUPPORTED DITHIOCARBOXYLATES
    CAIRON, P
    LABIAD, B
    VILLEMIN, D
    EUROPEAN POLYMER JOURNAL, 1988, 24 (07) : 697 - 698
  • [25] Synthesis of aminothiazoles: polymer-supported approaches
    Patil, R. V.
    Chavan, J. U.
    Beldar, A. G.
    RSC ADVANCES, 2017, 7 (38): : 23765 - 23778
  • [26] Soluble polymer-supported synthesis of isoxazoles
    Shang, YJ
    Wang, YG
    TETRAHEDRON LETTERS, 2002, 43 (12) : 2247 - 2249
  • [27] Soluble polymer-supported synthesis of benzodiazepinones
    Wu, CY
    Sun, CM
    BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2002, 12 (06) : 959 - 962
  • [28] Polymer-supported synthesis of bicyclic γ-lactams
    Zhu, T
    Yan, Z
    Chucholowski, A
    Li, RS
    JOURNAL OF COMBINATORIAL CHEMISTRY, 2005, 7 (04): : 520 - 522
  • [29] POLYMER-SUPPORTED BASES .10. SYNTHESIS OF PHOSPHATIDYLCHOLINES USING POLYMER-SUPPORTED OR FREE ACYLIMIDAZOLES
    TOMOI, M
    INOMATA, K
    KAKIUCHI, H
    SYNTHETIC COMMUNICATIONS, 1989, 19 (5-6) : 907 - 915
  • [30] The first synthesis of tetraglucosyl glucitol having phytoalexin-elicitor activity in rice cells based on a sequential glycosylation strategy
    Amaya, T
    Tanaka, H
    Yamaguchi, T
    Shibuya, N
    Takahashi, T
    TETRAHEDRON LETTERS, 2001, 42 (52) : 9191 - 9194
12345