RADICAL IONS CHEMISTRY - RADICAL-CATION REACTIONS

被引：0
|
作者：
PROUSEK, J
机构：
来源：
CHEMICKE LISTY | 1995年 / 89卷 / 03期
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暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The review deals with chemical reactions of radical cations. Only few examples are given. Intramolecular reactions of organic radical cations are illustrated on carbon-carbon bond cleavage reactions. Intermolecular reactions between radical cation and other molecule are illustrated on nucleophilic and pericyclic reactions, on radical cation reactions with free radicals and on radical cation-catalyzed chain oxygenation of olefins. The last chapter presents the reactions of radical cations formed on irradiated surfaces of semiconductors. On the basis of electron and/or hole transfer processes, new reaction mechanisms are discussed.
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页码：144 / 156
页数：13
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