PERSPECTIVES ON STRUCTURAL EFFECTS IN ORGANIC-CHEMISTRY

被引：8

作者：

TAFT, RW

机构：

来源：

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE | 1992年 / 89卷 / 7-8期

关键词：

D O I：

10.1051/jcp/1992891557

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Recent advances provide an optimistic perspective for useful quantitative predictions of structural effects in organic chemistry in terms of theoretical concepts. The following equilibria are examined as illustrations: (1) CH proton transfer acidities, experimental vs. theoretical calculations; (2) hydrogen-bond donor and acceptor strengths; (3) Li+ and K+ stability constants for organic bases; (4) gas vs. solution phase proton transfer equilibria.

引用

页码：1557 / 1566

页数：10

共 50 条

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