PERSPECTIVES ON STRUCTURAL EFFECTS IN ORGANIC-CHEMISTRY

被引：8
|
作者：
TAFT, RW
机构：
来源：
JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE | 1992年 / 89卷 / 7-8期
关键词：
D O I：
10.1051/jcp/1992891557
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Recent advances provide an optimistic perspective for useful quantitative predictions of structural effects in organic chemistry in terms of theoretical concepts. The following equilibria are examined as illustrations: (1) CH proton transfer acidities, experimental vs. theoretical calculations; (2) hydrogen-bond donor and acceptor strengths; (3) Li+ and K+ stability constants for organic bases; (4) gas vs. solution phase proton transfer equilibria.
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页码：1557 / 1566
页数：10
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