TEMPERATURE-DEPENDENCE OF NITROGEN BROADENING OF OZONE NU(3) ROVIBRATIONAL TRANSITIONS

被引：14

作者：

SPENCER, MN ^{[1
]}

CHACKERIAN, C ^{[1
]}

FLANNERY, C ^{[1
]}

STEINFELD, JI ^{[1
]}

机构：

[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1992年 / 48卷 / 09期

关键词：

D O I：

10.1016/0584-8539(92)80264-W

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

We report N2-broadening coefficients for rovibrational transitions of the nu3 band of ozone in the temperature range 180-296 K. We assume a power law dependence of the temperature for these coefficients, with a temperature exponent n. For the 21 transitions we measured, the average value of n is 0.74 and is well within experimental error of the theoretically predicted value of 0.77. The significance of this parameter in modeling atmospheric IR absorbance due to ozone is discussed.

引用

页码：1273 / 1281

页数：9

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