TEMPERATURE-DEPENDENCE OF NITROGEN BROADENING OF OZONE NU(3) ROVIBRATIONAL TRANSITIONS

被引：14
|
作者：
SPENCER, MN [1 ]
CHACKERIAN, C [1 ]
FLANNERY, C [1 ]
STEINFELD, JI [1 ]
机构：
[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1992年 / 48卷 / 09期
关键词：
D O I：
10.1016/0584-8539(92)80264-W
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
We report N2-broadening coefficients for rovibrational transitions of the nu3 band of ozone in the temperature range 180-296 K. We assume a power law dependence of the temperature for these coefficients, with a temperature exponent n. For the 21 transitions we measured, the average value of n is 0.74 and is well within experimental error of the theoretically predicted value of 0.77. The significance of this parameter in modeling atmospheric IR absorbance due to ozone is discussed.
引用
收藏
页码：1273 / 1281
页数：9
相关论文
共 50 条
12345