TEMPERATURE-DEPENDENCE OF NITROGEN BROADENING OF OZONE NU(3) ROVIBRATIONAL TRANSITIONS

被引：14
|
作者：
SPENCER, MN [1 ]
CHACKERIAN, C [1 ]
FLANNERY, C [1 ]
STEINFELD, JI [1 ]
机构：
[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1992年 / 48卷 / 09期
关键词：
D O I：
10.1016/0584-8539(92)80264-W
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
We report N2-broadening coefficients for rovibrational transitions of the nu3 band of ozone in the temperature range 180-296 K. We assume a power law dependence of the temperature for these coefficients, with a temperature exponent n. For the 21 transitions we measured, the average value of n is 0.74 and is well within experimental error of the theoretically predicted value of 0.77. The significance of this parameter in modeling atmospheric IR absorbance due to ozone is discussed.
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收藏
页码：1273 / 1281
页数：9
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