A FACILE SYNTHESIS OF THE INTERMEDIATES OF THE BICYCLIC ORGANIC-BASES - DBU AND TBD

被引：5
|
作者：
CHENG, XH [1 ]
LIU, FC [1 ]
机构：
[1] YUNNAN UNIV,DEPT CHEM,KUNMING 650091,PEOPLES R CHINA
来源：
SYNTHETIC COMMUNICATIONS | 1993年 / 23卷 / 22期
关键词：
D O I：
10.1080/00397919308011178
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Intermediates of DBU and TBD, N-(3-aminoproply) - epsilon-caprolactam and bis-(3-aminopropyl)-amine were prepared by the hydrogenolysis of N-(2-cyanoethyl) - epsilon - caprolactam and di- (beta-cyanoethyl)amine respectively over Raney-Ni in the presence of NaBH4 under atmospheric pressure with mild condition and good yield.
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收藏
页码：3191 / 3194
页数：4
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