SYNTHESIS AND DECOMPOSITION OF BENZENEDIAZONIUM TRIS((TRIFLUOROMETHYL)SULFONYL)METHANIDE, C6H5N2+(CF3SO2)3C-, AND BENZENEDIAZONIUM BIS((TRIFLUOROMETHYL)SULFONYL)AMIDE, C6H5N2+(CF3SO2)2N-, AND THE CYCLIC ANALOG, C6H5N2+SO2(CF2)3SO2N-1

被引：24

作者：

ZHU, SZ ^{[1
]}

DESMARTEAU, DD ^{[1
]}

机构：

[1] CLEMSON UNIV,HL HUNTER CHEM LAB,CLEMSON,SC 29634

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 02期

关键词：

D O I：

10.1021/ic00054a018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Phenyltris((trifluoromethyl)sulfonyl)methane (CF3SO2)3CC6H5, and its isomeric ester (CF3SO2)2C=SCF3(O)OC6H5 are formed by the thermal decomposition of benzenediazonium tris((trifluoromethyl)sulfonyl)methanide, C6H5N2+SO2(CF2)3SO2N-, which was prepared by treatment of tris((trifluoromethyl)sulfonyl)methane, (CF3SO2)3CH, with benzenediazonium chloride. Similarly, pyrolysis of benzenediazonium bis((trifluoromethyl)sulfonyl)amide, C6H5N2+(CF3SO2)2N-, and the cyclic analog C6H5N2+SO2(CF2)3SO2N-, prepared analogously from the corresponding sulfonimides, yields the N-phenyl and O-phenyl isomers (CF3SO2)2NC6H5, CF3SO2N=SCF3(O)OC6H5, SO2(CF2)3SO2NC6H5, and SO2(CF2)3S(O)(=N)OC6H5, respectively.

引用

页码：223 / 226

页数：4

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