Crystal structure of (E)-4-{1-[2-(carbamothioyl)hydrazin-1-ylidene]ethyl}-phenyl 4-methylbenzoate

被引：2

作者：

Mani, Karthik Ananth ^{[1
]}

Viswanathan, Vijayan ^{[2
]}

Narasimhan, S. ^{[1
]}

Velmurugan, Devadasan ^{[2
]}

机构：

[1] Asthagiri Herbal Res Fdn, Dept Chem, Madras 600096, Tamil Nadu, India

[2] Univ Madras, Ctr Adv Study Crystallog & Biophys, Guindy Campus, Madras 600025, Tamil Nadu, India

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; thiosemicarbazones derivatives; biological activity; hydrogen bonding; ester;

D O I：

10.1107/S2056989014026942

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, C17H17N3O2S, consists of two independent molecules, A and B, with different conformations: in molecule A, the dihedral angles between the central benzene ring and the pendant tolyl and carbamothioylhydrazono groups are 71.12 (9) and 5.95 (8)degrees, respectively. The corresponding angles in molecule B are 50.56 (12) and 26.43 (11)degrees, respectively. Both molecules feature an intramolecular N-H center dot center dot center dot N hydrogen bond, which closes an S(5) ring. In the crystal, molecules are linked by N-H center dot center dot center dot O, NH center dot center dot center dot S and C-H center dot center dot center dot O hydrogen bonds, generating a threedimensional network.

引用

页码：O43 / +

页数：12

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