Crystal structure of (E)-4-{1-[2-(carbamothioyl)hydrazin-1-ylidene]ethyl}-phenyl 4-methylbenzoate

被引：2
|
作者：
Mani, Karthik Ananth [1 ]
Viswanathan, Vijayan [2 ]
Narasimhan, S. [1 ]
Velmurugan, Devadasan [2 ]
机构：
[1] Asthagiri Herbal Res Fdn, Dept Chem, Madras 600096, Tamil Nadu, India
[2] Univ Madras, Ctr Adv Study Crystallog & Biophys, Guindy Campus, Madras 600025, Tamil Nadu, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; thiosemicarbazones derivatives; biological activity; hydrogen bonding; ester;
D O I：
10.1107/S2056989014026942
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, C17H17N3O2S, consists of two independent molecules, A and B, with different conformations: in molecule A, the dihedral angles between the central benzene ring and the pendant tolyl and carbamothioylhydrazono groups are 71.12 (9) and 5.95 (8)degrees, respectively. The corresponding angles in molecule B are 50.56 (12) and 26.43 (11)degrees, respectively. Both molecules feature an intramolecular N-H center dot center dot center dot N hydrogen bond, which closes an S(5) ring. In the crystal, molecules are linked by N-H center dot center dot center dot O, NH center dot center dot center dot S and C-H center dot center dot center dot O hydrogen bonds, generating a threedimensional network.
引用
收藏
页码：O43 / +
页数：12
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