ASYMMETRIC EPOXIDATION OF FLUORINATED ALLYLIC ALCOHOLS

被引：14
|
作者：
GOSMINI, C [1 ]
DUBUFFET, T [1 ]
SAUVETRE, R [1 ]
NORMANT, JF [1 ]
机构：
[1] UNIV PARIS 06,CHIM ORGANOELEMENTS LAB,TOUR 44-45,4 PL JUSSIEU,F-75252 PARIS 05,FRANCE
来源：
TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 03期
关键词：
D O I：
10.1016/S0957-4166(00)82361-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The asymmetric epoxidation of an alpha, beta-difluoro primary allylic alcohol, and of two alpha-fluoro secondary allylic alcohols follows the pattern known with non fluorinated analogs. The fluoro epoxides thus formed can be transformed into chiral alpha-ketols and into an alpha-fluoroacid.
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页码：223 / 230
页数：8
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