Epoxidation of allylic alcohols by polymeric Ti(IV) glycolates

被引：0
|
作者：
Massa, A [1 ]
Scettri, A [1 ]
机构：
[1] Univ Salerno, Dipartimento Chim, I-84081 Baronissi, Salerno, Italy
来源：
SYNLETT | 2000年 / 09期
关键词：
epoxidations; titanium; allylic alcohols; diastereoselectivity; regioselectivity;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Chemo- and diastereoselective epoxidation of allylic alcohols can be performed by t-butyl hydroperoxide in the presence of easily accessible, polymeric titanium(IV) glycolates under heterogeneous conditions. No lowering of the activity of the recovered catalyst is observed after 3 cycles of epoxidation.
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页码：1348 / 1350
页数：3
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