NONCLASSICAL STEADY-STATE REACTION-RATES FOR THE DIFFUSION MEDIATED REACTION A+A-]0 WITH PARTICLE DECAY

被引：1
|
作者：
MOLSKI, A [1 ]
机构：
[1] UNIV CALIF DAVIS,DEPT CHEM,DAVIS,CA 95616
来源：
CHEMICAL PHYSICS LETTERS | 1991年 / 178卷 / 01期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/0009-2614(91)85050-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The effective steady state rate constants for the bimolecular annihilation A + A --> 0 accompanied by unimolecular decay, A --> 0, and particle generation, S --> A, are calculated in spatial dimensions d = 1, 2, 3 using the fluctuation dissipation theory. Non-classical (concentration dependent) rate constants are found for the low dimensional systems (d = 1, 2) when the bimolecular process dominates unimolecular decay.
引用
收藏
页码：43 / 48
页数：6
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