Crystal structure of poly[[mu(3)-4,4'-(4,4'bipyridine-2,6-diyl)dibenzoato]{mu(2)-4-[6(4-carboxyphenyl)-4,4'-bipyridin-4'- ium2-yl]benzoato}manganese(II)] hemihydrate]

被引：0

作者：

Li, Yaping ^{[1
]}

Sung, Dajun ^{[2
]}

Ming, Julia ^{[3
]}

Han, Liying ^{[4
]}

Su, Guanfang ^{[1
]}

机构：

[1] Second Hosp Jilin Univ, Dept Ophthalmol, Changchun 130041, Jilin, Peoples R China

[2] Jilin Univ, China Japan Union Hosp, Dept Vasc Surg, 126 Xiantai St, Changchun 130033, Jilin, Peoples R China

[3] St Eriks Eye Hosp, Karolinska Inst, SE-11282 Stockholm, Sweden

[4] Second Hosp Jilin Univ, Dept Gynaecol, Changchun 130041, Jilin, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

crystal structure; Mn complex; metal-organic coordination polymer; hydrogen bonds;

D O I：

10.1107/S160053681402279X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, {[Mn(C24H14N2O4)(C24H16N2O4)]center dot- 0.5H(2)O} n, was obtained by the reaction of manganese nitrate with the ligand 4,4'-(4,4'-bipyridine-2,6-diyl) dibenzoic acid under hydrothermal conditions. The water O atom is located on a twofold rotation axis. The Mn2+ ion is heptacoordinated by six O atoms and one N atom from the ligands. In this structure, the ligands adopts two different forms, one completely deprotonated and one with a protonated N atom (pyridinium) and a carboxylic acid function. In the crystal, N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds consolidate the packing, forming a three-dimensional framework.

引用

页码：M374 / +

页数：14

共 50 条

[1] Poly[(μ2-4,4′-bipyridine)tris[μ4-(E)-4,4′(ethene-1,2-diyl)dibenzoato]zinc(II)]
Wang, Huan-Yu
Gao, Shan
Zhao, Jing-Gui
Ng, Seik Weng
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M3298 - M3300
[2] Poly[[diaquabis{mu-4-[6-(4-carboxyphenyl)-4,4 '-bipyridin-2-yl]benzoato-kappa O-2:N4 '}zinc] dimethylformamide tetrasolvate]
Ge, Xin
Song, Shuyan
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1413 - +
[3] 2′,6′-Bis(4-carboxyphenyl)-4,4′-bipyridin-1-ium nitrate 0.25-hydrate
Li, Yaping
Zang, Hu
Su, Guanfang
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : O43 - +
[4] Poly[[diaquabis{mu-4-[6-(4-carboxyphenyl)-4,4'-bipyridin-2-yl]benzoato-kappa O-2:N-1'}copper(II)] dimethylformamide tetrasolvate]
Sun, Yabin
Song, E.
Wang, Daguang
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M202 - +
[5] THE CRYSTAL-STRUCTURES OF 4,4'-BIPYRIDINIUM MU-(4,4'-BIPYRIDINE)BIS[DIAQUATETRANITRATONEODYMATE(III)]-TRIS(4,4'-BIPYRIDINE) AND A 2ND MONOCLINIC FORM OF TRIAQUATRINITRATOHOLMIUM(III)-BIS (4,4'-BIPYRIDINE)
WEAKLEY, TJR
INORGANICA CHIMICA ACTA-F-BLOCK ELEMENTS ARTICLES AND LETTERS, 1984, 95 (06): : 317 - 322
[6] catena-Poly[[diaqua[mu(2)-4-(4-carboxyphenoxy)benzoato](mu(2)-4,4 '-oxydibenzoato)praseodymium(III)] monohydrate]
Li, Ping
Su, Duo-Meng
Zheng, Chang-Ge
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M586 - +
[7] Dimethyl 4,4′-(pyridine-2,6-diyl)dibenzoate
Cui, Yue
Gao, Qian
Wang, Huan-Huan
Wang, Lin
Xie, Ya-Bo
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O2975 - U1580
[8] Catena-poly[[[diaquadinitratocopper(II)]-μ-4,4′-bipyridine] hemihydrate]
Lin, Xu-Cong
Yin, Hua
Lin, Yun
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M1467 - U310
[9] Poly[[[aquamanganese(II)]-μ2-4,4′-bipyridine-μ3-succinato] 4,4′-bipyridine hemisolvate]
Ma, CB
Chen, F
Zhang, CX
Hu, MQ
Chen, CN
Liu, QT
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 (06): : M285 - M287
[10] Hydrothermal synthesis and crystal structure of a layered coordination polymer:: [Zn3(C2O4)3(4,4′-bipy)4]n (4,4′-bipy=4,4′-bipyridine)
Hao, N
Shen, EH
Li, YG
Wang, EB
Hu, CW
Xu, L
JOURNAL OF MOLECULAR STRUCTURE, 2004, 691 (1-3) : 273 - 277

← 1 2 3 4 5 →