catena-Poly[[diaqua[mu(2)-4-(4-carboxyphenoxy)benzoato](mu(2)-4,4 '-oxydibenzoato)praseodymium(III)] monohydrate]

被引：0
|
作者：
Li, Ping [1 ]
Su, Duo-Meng [1 ]
Zheng, Chang-Ge [1 ]
机构：
[1] Jiangnan Univ, Sch Chem & Mat Engn, 1800 Lihu Rd, Wuxi 214122, Jiangsu, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
D O I：
10.1107/S1600536813026421
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, {[Pr(C14H8O5)(C14H9O5)(H2O)(2)]center dot-H2O}(n), the Pr III cation is eight-coordinated by six carboxyl O atoms from both a monoanionic 4-(4-carboxyphenoxy)benzoate and a dianionic 4,4'-oxydibenzoate ligand (four bridging with two from a bidentate chelate interaction), and two O-atom donors from water molecules. A single water molecule of solvation is also present. The complex units are linked through carboxyl O: O' bridges giving a two-dimensional sheet polymer lying parallel to (001). An overall threedimensional network structure is generated through intermolecular carboxylic acid and water O-H center dot center dot center dot O hydrogen bonds and weak C-H center dot center dot center dot O interactions.
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收藏
页码：M586 / +
页数：12
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