Crystal structure of poly[[mu(3)-4,4'-(4,4'bipyridine-2,6-diyl)dibenzoato]{mu(2)-4-[6(4-carboxyphenyl)-4,4'-bipyridin-4'- ium2-yl]benzoato}manganese(II)] hemihydrate]

被引：0

作者：

Li, Yaping ^{[1
]}

Sung, Dajun ^{[2
]}

Ming, Julia ^{[3
]}

Han, Liying ^{[4
]}

Su, Guanfang ^{[1
]}

机构：

[1] Second Hosp Jilin Univ, Dept Ophthalmol, Changchun 130041, Jilin, Peoples R China

[2] Jilin Univ, China Japan Union Hosp, Dept Vasc Surg, 126 Xiantai St, Changchun 130033, Jilin, Peoples R China

[3] St Eriks Eye Hosp, Karolinska Inst, SE-11282 Stockholm, Sweden

[4] Second Hosp Jilin Univ, Dept Gynaecol, Changchun 130041, Jilin, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

crystal structure; Mn complex; metal-organic coordination polymer; hydrogen bonds;

D O I：

10.1107/S160053681402279X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, {[Mn(C24H14N2O4)(C24H16N2O4)]center dot- 0.5H(2)O} n, was obtained by the reaction of manganese nitrate with the ligand 4,4'-(4,4'-bipyridine-2,6-diyl) dibenzoic acid under hydrothermal conditions. The water O atom is located on a twofold rotation axis. The Mn2+ ion is heptacoordinated by six O atoms and one N atom from the ligands. In this structure, the ligands adopts two different forms, one completely deprotonated and one with a protonated N atom (pyridinium) and a carboxylic acid function. In the crystal, N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds consolidate the packing, forming a three-dimensional framework.

引用

页码：M374 / +

页数：14

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