(CH3)3IN.1,4-X2C4H8 (WITH X=O, S), 2 STABLE ADDUCTS WITH CHAIN STRUCTURE

被引：8

作者：

BLANK, J ^{[1
]}

HAUSEN, HD ^{[1
]}

SCHWARZ, W ^{[1
]}

WEIDLEIN, J ^{[1
]}

机构：

[1] UNIV STUTTGART,INST ANORGAN CHEM,PFAFFENWALDRING 55,W-7000 STUTTGART 80,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 443卷 / 02期

关键词：

D O I：

10.1016/0022-328X(93)80292-J

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Trimethylindium forms stable, high-melting 1:1 adducts with 1,4-dioxane and 1,4-dithiane, respectively. For both compounds spectroscopic investigations (mass spectrometry, H-1 and C-13 NMR, IR and Raman) indicate chain structures with five-fold coordinated indium atoms in the solid state. The X-ray structure determination of (CH3)3In . S2C4H8 shows infinite chains of nearly planar In(CH3)3 units bridged by the two S atoms of the dithiane ligands. The methyl groups of all trimethylindium moieties of one chain are eclipsed, and the heterocyclic rings have the chair conformation. The compound crystallizes in the triclinic space group P1BAR (Z = 2); the structure was refined to an R value of 0.024.

引用

页码：145 / 151

页数：7

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