(CH3)3IN.1,4-X2C4H8 (WITH X=O, S), 2 STABLE ADDUCTS WITH CHAIN STRUCTURE

被引：8
|
作者：
BLANK, J [1 ]
HAUSEN, HD [1 ]
SCHWARZ, W [1 ]
WEIDLEIN, J [1 ]
机构：
[1] UNIV STUTTGART,INST ANORGAN CHEM,PFAFFENWALDRING 55,W-7000 STUTTGART 80,GERMANY
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 443卷 / 02期
关键词：
D O I：
10.1016/0022-328X(93)80292-J
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Trimethylindium forms stable, high-melting 1:1 adducts with 1,4-dioxane and 1,4-dithiane, respectively. For both compounds spectroscopic investigations (mass spectrometry, H-1 and C-13 NMR, IR and Raman) indicate chain structures with five-fold coordinated indium atoms in the solid state. The X-ray structure determination of (CH3)3In . S2C4H8 shows infinite chains of nearly planar In(CH3)3 units bridged by the two S atoms of the dithiane ligands. The methyl groups of all trimethylindium moieties of one chain are eclipsed, and the heterocyclic rings have the chair conformation. The compound crystallizes in the triclinic space group P1BAR (Z = 2); the structure was refined to an R value of 0.024.
引用
收藏
页码：145 / 151
页数：7
相关论文
共 50 条
  • [1] Mononuclear tantalum (V) pentalene complexes:: synthesis of [Ta{η8-C8H4(1,4-SiiPr3)2}X3] (X = CH3, Cl, I) and the X-ray crystal structures of [Ta{η8-C8H4(1,4-SiiPr3)2}(CH3)3], [Ta{η8-C8H4(1,4-SiiPr3)2}(CH3)2Cl], [Ta {η8-C8H4(1,4-SiiPr3)2}(CH3)Cl2] and [Ta{η8-C8H4(1,4-SiiPr3)2}I3]
    Cloke, FGN
    Hitchcock, PB
    Kuchta, MC
    Morley-Smith, NA
    POLYHEDRON, 2004, 23 (17) : 2625 - 2630
  • [2] CRYSTAL AND MOLECULAR STRUCTURE OF [AL(CH3)3]2.C4H8O2
    ATWOOD, JL
    STUCKY, GD
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (21) : 5362 - &
  • [3] An Experimental Exploration of C --H•••X Hydrogen Bond in [CHCl3 X(CH3)2] Complexes (X=O, S, and Se)
    Pal, Dhritabrata
    Charaya, Heena
    Chakraborty, Shamik
    CHEMPHYSCHEM, 2023, 24 (15)
  • [4] Synthesis and Spectroscopic Characterization of Mixed Diamidophosphoric Acid Esters: X-Ray Crystal Structure of [(CH3)2N]-[p-H3C-C6H4-O]P(O)X (X=NHC(CH3)3 and p-H3C-C6H4-NH)
    Ghadimi, Saied
    Pourayoubi, Mehrdad
    Valmoozi, Ali Asghar Ebrahimi
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2009, 64 (05): : 565 - 569
  • [5] EXCESS MOLAR VOLUMES AT THE TEMPERATURE 298.15-K OF (X1C2H5CO2(CH2)2CH3+X2CL(CH2)5CH3+(1-X1-X2)C-C6H12), (X1C2H5CO2(CH2)2CH3+X2CL(CH2)5CH3+(1-X1-X2)CH3(CH2)4CH3), AND (X1C2H5CO2(CH2)2CH3+X2C-C6H12+(1-X1-X2)CH3(CH2)4CH3)
    SOUZA, MJ
    JIMENEZ, E
    LEGIDO, JL
    FERNANDEZ, J
    MARTELL, EP
    ANDRADE, MIP
    JOURNAL OF CHEMICAL THERMODYNAMICS, 1992, 24 (02): : 119 - 128
  • [6] Nonthermal rate constants for CH4* + X → CH3 + HX, X = H, O, OH, and O2
    Jasper, Ahren W.
    Sivaramakrishnan, Raghu
    Klippenstein, Stephen J.
    JOURNAL OF CHEMICAL PHYSICS, 2019, 150 (11):
  • [7] Systematic Characterization of Gas Phase Binary Pre-Nucleation Complexes Containing H2SO4 + X, [X = NH3, (CH3)NH2, (CH3)2NH, (CH3)3N, H2O, (CH3)OH, (CH3)2O, HF, CH3F, PH3, (CH3)PH2, (CH3)2PH, (CH3)3P, H2S, (CH3)SH, (CH3)2S, HCI, (CH3)CI)]. A Computational Study
    Sebastianelli, Paolo
    Cometto, Pablo M.
    Pereyra, Rodolfo G.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2018, 122 (08): : 2116 - 2128
  • [8] Homoleptic Tris(α,ω-alkanediyl)yttriates of the Type [{Li(dme)}3{Y(CH2-X-CH2)3}] (X = C2H4, C3H6, Si(CH3)2)
    Fischer, Reinald
    Bode, Stefan
    Koehler, Mathias
    Langer, Jens
    Goerls, Knar
    Hager, Martin D.
    Schubert, Ulrich S.
    Westerhausen, Matthias
    ORGANOMETALLICS, 2015, 34 (01) : 23 - 31
  • [9] STRUCTURAL INVESTIGATIONS OF COMPOUNDS ME4SBX WITH X= H3C(O)C-N-N-C(O)CH3 = DAH, F AND OP(S) (CH3)2
    SCHWARZ, W
    GUDER, HJ
    ACTA CRYSTALLOGRAPHICA SECTION A, 1978, 34 : S123 - S124
  • [10] THE X-RAY STRUCTURE DETERMINATION OF THE PYRROLIDES (CH3)(2)AL-C4H3NCH3 AND (CH3)(2)GA-N(CCH3)(4)
    HAUSEN, HD
    TODTMANN, J
    WEIDLEIN, J
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (03): : 430 - 433
12345