DYNAMICS OF THE THERMAL-DECOMPOSITION OF 2,3-DIAZABICYCLO[2.2.1]HEPT-2-ENE

被引：37

作者：

SIMPSON, CJSM ^{[1
]}

WILSON, GJ ^{[1
]}

ADAM, W ^{[1
]}

机构：

[1] UNIV WURZBURG,INST ORGAN CHEM,W-8700 WURZBURG,GERMANY

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1991年 / 113卷 / 13期

关键词：

D O I：

10.1021/ja00013a002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dynamics of the thermal decomposition of 2,3-diazabicyclo[2.2.l]hept-2-ene (DBH) have been investigated over the temperature range 900-1400 K. A tunable continuous wave CO laser was used to follow the vibrational energy content of the coupled CO-N2 system from the initial to the equilibrium conditions. It has been shown that the N2 iS born with very little vibrational energy. while the bicyclo[2.1.0]pentane is born with an excess over the equilibrium distribution. These results provide clear evidence against the concerted decomposition mechanism.

引用

页码：4728 / 4732

页数：5

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