ALPHA-METHOXYLATION OF UNSATURATED CARBONYL-COMPOUNDS

被引：8

作者：

FEUERER, A ^{[1
]}

SEVERIN, T ^{[1
]}

机构：

[1] UNIV MUNICH,INST PHARM & LEBENSMITTELCHEM,D-80333 MUNICH,GERMANY

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 20期

关键词：

D O I：

10.1021/jo00099a037

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

alpha-Methoxylation of enals or enones can be performed in high yield by a simple one-pot reaction sequence: Bromination of unsaturated hydrazones, HBr-elimination, and addition of methanol leads to the formation of beta-bromo-alpha-methoxy hydrazones (11), which after hydrolysis and HBr-elimination yields the alpha-methoxy enals or alpha-methoxy enones (13), respectively.

引用

页码：6026 / 6029

页数：4

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