Zinc complexes of dipyridyl-triazoles

被引:28
|
作者
Hartmann, U [1 ]
Vahrenkamp, H [1 ]
机构
[1] UNIV FREIBURG,INST ANORGAN & ANALYT CHEM,D-79104 FREIBURG,GERMANY
关键词
zinc complexes; drug-related ligand complexes; crystal structures;
D O I
10.1016/0020-1693(95)04712-3
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The ligands 3,5-di(2-pyridyl)-1,2,4-triazole (L) and 3,5-di(2-pyridyl)-4-amino-1,2,4-triazole (L') were reacted with zinc salts. With ZnCl2 1:1 complexes were obtained. Zn(NO3)(2), Zn(ClO4)(2) and Zn(BF4)(2) produced 2:1 complexes, NMR and IR data indicate varying bonding modes of the ligands and anions. A crystal structure determination of [(L')(2)Zn(H2O)(2)](ClO4)(2) has shown the metal to be octahedrally coordinated by two water molecules and one triazole and pyridine nitrogen atom each of the two ligands L'.
引用
收藏
页码:13 / 17
页数:5
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