Crystal structure of 1-(2-chloroacetyl)-2,6-bis(4-fluorophenyl)-3,3-dimethylpiperidin-4-one

被引:1
|
作者
Jothivel, S. [1 ]
Kotoky, Jibon [2 ]
Kabilan, S. [1 ]
机构
[1] Annamalai Univ, Dept Chem, Chidambaram 608002, Tamil Nadu, India
[2] IASST, Div Life Sci Cent Instrumentat Facil, Gauhati 781035, Assam, India
关键词
Piperidone; weak hydrogen bonds; crystal structure;
D O I
10.1107/S1600536814021278
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title molecule, C21H20ClF2NO2, the piperidine ring adopts a slightly distorted boat conformation. The two benzene rings form a dihedral angle of 87.43 (1)degrees. A weak intramolecular C-H center dot center dot center dot pi interaction is observed. In the crystal, weak C-H center dot center dot center dot O hydrogen bonds and weak C-H center dot center dot center dot pi interactions connect the molecules, forming a three-dimensional network.
引用
收藏
页码:262 / +
页数:9
相关论文
共 50 条
  • [41] 3-(4-Fluorophenyl)-1-(4-methoxyphenyl)-prop-2-en-1-one
    Zhao, Pu-Su
    Wang, Xian
    Guo, Huan-Mei
    Jian, Fang-Fang
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O1402 - U2963
  • [42] 1-(4-fluorophenyl)-3-(4-methoxyphenyl)prop-2-en-1-one
    Harrison, William T. A.
    Yathirajan, H. S.
    Anilkumar, H. G.
    Sarojini, B. K.
    Narayana, B.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : O3251 - O3253
  • [43] 1-(4-Fluorophenyl)-3-(2,4,5-trimethoxyphenyl)prop-2-en-1-one
    Teh, Jeannie Bee-Jan
    Patil, P. S.
    Fun, Hoong-Kun
    Razak, Ibrahim Abdul
    Dharmaprakash, S. M.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O54 - O56
  • [44] 1-(4-Fluorophenyl)-2-(phenylsulfonyl)ethanone
    Abdel-Aziz, Hatem A.
    Ghabbour, Hazem A.
    Chantrapromma, Suchada
    Fun, Hoong-Kun
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1659 - +
  • [45] 1-[Bis(4-fluorophenyl) methyl]-4-[2(naphthalen-2-yloxy) ethyl] piperazine
    Zhong, Yan
    Wu, Bin
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1974 - +
  • [46] Synthesis, Characterization, and Crystal Structure of (2E)-3-(4-Fluorophenyl)-1-(2-hydroxyphenyl)prop-2-en-1-one
    Cathryn A. Slabber
    Craig D. Grimmer
    Orde Q. Munro
    Ross S. Robinson
    Journal of Chemical Crystallography, 2018, 48 : 213 - 219
  • [47] 1-[Bis(4-fluorophenyl)methyl]-4-[2-(2-methylphenoxy)ethyl]piperazine
    Dai, Zhao-Hui
    Zhong, Yan
    Wu, Bin
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1077 - +
  • [48] Crystal structure and DFT studies of (E)-1-(4-fluorophenyl)-3-(1H-indol-1-yl)-4-styrylazetidin-2-one
    Gummidi, Lalitha
    Kerru, Nagaraju
    Ibeji, Collins U.
    Singh, Parvesh
    JOURNAL OF MOLECULAR STRUCTURE, 2019, 1187 : 50 - 58
  • [49] Synthesis, Characterization, and Crystal Structure of (2E)-3-(4-Fluorophenyl)-1-(2-hydroxyphenyl)prop-2-en-1-one
    Slabber, Cathryn A.
    Grimmer, Craig D.
    Munro, Orde Q.
    Robinson, Ross S.
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2018, 48 (04) : 213 - 219
  • [50] (E)-3-(4-Chlorophenyl)-1-(4-fluorophenyl) prop-2-en-1-one
    Fun, Hoong-Kun
    Chia, Tze Shyang
    Sapnakumari, M.
    Narayana, B.
    Sarojini, B. K.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O629 - U1573