ALKYLATION REACTIONS OF 4,5-BIS(TRIFLUOROMETHYL)-1,3-DITHIOLE-2-THIONE - A 1ST X-RAY STRUCTURE DETERMINATION OF A 2-ALKYLTHIO-1,3-DITHIOLIUM SALT

被引：5
|
作者：
FRASCH, M [1 ]
MONO, S [1 ]
PRITZKOW, H [1 ]
SUNDERMEYER, W [1 ]
机构：
[1] UNIV HEIDELBERG,INST ANORGAN CHEM,NEUENHEIMER FELD 270,W-6900 HEIDELBERG 1,GERMANY
来源：
CHEMISCHE BERICHTE-RECUEIL | 1993年 / 126卷 / 01期
关键词：
1,3-DITHIOLE-2-THIONE, 4,5-BIS(TRIFLUOROMETHYL)-1,3-DITHIOLE-2-THIONE; ALKYLATION; PERFLUOROBUTANESULFONIC ACID; ALKYL ESTERS; TRIETHYLOXONIUM HEXACHLOROANTIMONATE; 1,3-DITHIOLIUM SALTS, 2-ALKYLTHIO-1,3-DITHIOLIUM;
D O I：
10.1002/cber.19931260138
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The 2-alkylthio-1,3-dithiolium salts 2a-e have been prepared by reaction of 4,5-bis(trifluoromethyl)-1,3-dithiole-2-thione (1) with strong alkylating agents like alkyl perfluorobutanesulfonates or Meerwein salts. The first X-ray structure determination shows a localized double bond in the ring system combined with a trithiocarbenium ion in 2e.
引用
收藏
页码：273 / 275
页数：3
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