THE INFLUENCE OF SUBSTITUENTS AT PROCHIRAL CENTERS ON THE STEREOSELECTIVITY OF ENOLATE RADICALS

被引：0
|
作者：
GIESE, B [1 ]
DAMM, W [1 ]
WITZEL, T [1 ]
ZEITZ, HG [1 ]
机构：
[1] TH DARMSTADT,INST ORGAN CHEM,D-64287 DARMSTADT,GERMANY
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 44期
关键词：
D O I：
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中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Increasing bulk of substituent Rat the prochiral center of radicals 10 and 13 reverses the stereochemistry of the reaction. This effect is caused by the interaction between the groups at the stereogenic and the prochiral center.
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页码：7053 / 7056
页数：4
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