NEW COPOLYMETHACRYLATES WITH AZO-CHROMOPHORES IN THE SIDE-CHAIN

被引:0
|
作者
CZAPLA, S
RUHMANN, R
RUBNER, J
ZSCHUPPE, V
WOLFF, D
机构
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中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthesis and characterization of new poly({6-[4-(4-cyanophenylcarbamoyl)phenoxy]hexyl methacrylate}-co-{6-[4-(4-cyanophenylazo)phenoxy]hexyl methacrylate}) are reported. Their liquid-crystalline properties are investigated using differential scanning calorimetry, polarizing microscopy and X-ray diffraction techniques. The glass transition temperatures and the clearing points can be influenced by variation of the copolymer composition. The substances offer a relatively broad temperature range of mesomorphic properties suitable for photochemical studies.
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页码:243 / 250
页数:8
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