TRANSITION METAL DICHALCOGENIDES DISCUSSION AND INTERPRETATION OF OBSERVED OPTICAL, ELECTRICAL AND STRUCTURAL PROPERTIES

被引:3625
作者
WILSON, JA
YOFFE, AD
机构
[1] Cavendish Laboratory, Cambridge
关键词
D O I
10.1080/00018736900101307
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The transition metal dichalcogenides are about 60 in number. Two-thirds of these assume layer structures. Crystals of such materials can be cleaved down to less than 1000 Å and are then transparent in the region of direct band-to-band transitions. The transmission spectra of the family have been correlated group by group with the wide range of electrical and structural data available to yield useful working band models that are in accord with a molecular orbital approach. Several special topics have arisen; these include exciton screening, d-band formation, and the metal/insulator transition; also magnetism and superconductivity in such compounds. High pressure work seems to offer the possibility for testing the recent theory of excitonic insulators. © 1969 Taylor & Francis Group, LLC.
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页码:193 / +
页数:1
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