X-RAY CRYSTAL-STRUCTURE OF BIS(4-BENZOYL-2,4-DIHYDRO-5-METHYL-2-PHENYL-3H-PYRAZOL-3-ONATO) DIBUTYL TIN(IV), C42H44N4O4SN, WITH TRANS RR SN CONFIGURATION

被引：26
|
作者：
SAXENA, S
BOHRA, R
RAI, AK
机构：
[1] Department of Chemistry, University of Rajasthan, Jaipur
来源：
INORGANICA CHIMICA ACTA | 1990年 / 173卷 / 02期
关键词：
D O I：
10.1016/S0020-1693(00)80212-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A dialkyl tin complex of composition Bu2SnL2 (I) (L is a monofunctional bidentate ligand) has been made by reaction of ClBu2SnOSnBu2Cl with the substituted pyrazolone, PhCOC:C(OH)N(Ph)N:CCH3, in dry benzene. Crystals of I (M= 787.5) are monoclinic, space group P21/C, a= 9.714(6), b=19.621(6), c=22.68(1) Å, β=114.00(4)°, V=3949.2 Å3, Z=4, Dcalc=1.3240 cm-3, λ(Mo Kα)=0.71069 Å, μ=6.960 cm-1, T=295 K, F(000)=1624, R=0.0628 for 2187 unique reflections. The molecule has a distorted octahedral geometry with Bu groups trans to each other. Four oxygen atoms of the pyrazolone moieties and the central Sn atom lie in the same plane. © 1990.
引用
收藏
页码：191 / 194
页数：4
相关论文
共 50 条
  • [31] Bis{4-[(Z)-(2,4-dimethylphenylamino)phenylmethylene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onato-κ2N,O}(ethanol-κO)nickel(II)
    Ma, Rong-Ming
    Sun, Shao-Fa
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M2723 - M2724
  • [32] Crystal structure of (4Z)-4-((4-iodoanilino)(phenyl)methyl]-3-methyl-1-phenyl-1H-pyrazol-5-(4H)-one, C23H18IN3O
    Xu, Liang
    Yang, Yan-Yun
    Wang, Bing
    Kang, Ting-Guo
    Li, Yan-Li
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2012, 227 (03): : 377 - 378
  • [33] THE USE OF SOFT DONOR LIGANDS, 4-BENZOYL-2,4-DIHYDRO-5-METHYL-2-PHENYL-3H-PYRAZOL-3-THIONE AND 4,7-DIPHENYL-1,10-PHENANTHROLINE, FOR IMPROVED SEPARATION OF TRIVALENT AMERICIUM AND EUROPIUM
    ENSOR, DD
    JARVINEN, GD
    SMITH, BF
    SOLVENT EXTRACTION AND ION EXCHANGE, 1988, 6 (03) : 439 - 445
  • [34] CRYSTAL-STRUCTURE OF BETA-C.I. SOLVENT YELLOW 18, 4(2', 4'-DIMETHYL PHENYL HYDRAZONO)-5-METHYL-2-PHENYL-3H-PYRAZOL-3-ONE
    WHITAKER, A
    JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH, 1992, 22 (04): : 385 - 390
  • [35] SEPARATION STUDIES OF YTTRIUM(III) AND LANTHANIDE(III) IONS WITH 4-BENZOYL-2,4-DIHYDRO-5-METHYL-2-PHENYL-3H-PYRAZOL-3-THIONE AND TRIOCTYLPHOSPHINE OXIDE USING A ROBOTIC EXTRACTION SYSTEM
    NEKIMKEN, HL
    SMITH, BF
    JARVINEN, GD
    BARTHOLDI, CS
    SOLVENT EXTRACTION AND ION EXCHANGE, 1992, 10 (03) : 419 - 429
  • [36] Crystal structure of tricyclohexyl[4-(4H-1,2,4-triazol-4-yl)-benzoato-κO]tin(IV), C27H39N3O2Sn
    Qing, Jingjing
    Tian, Jie
    Deng, Xin
    Zhang, Fuxing
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2024, 239 (01): : 25 - 27
  • [37] AQUATRIMETHYL(TRICYANOMETHANIDO)TIN(IV), [SN(CH3)3(C4N3)(H2O)]
    BRITTON, D
    CHOW, YM
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1983, 39 (NOV): : 1539 - 1540
  • [38] Distribution studies of actinides using a tetradentate extractant, 4,4′-nonanedioyl-bis (2,4-dihydro-5-methyl-2-phenyl -3h-pyrazol-3-o ne)
    Ensor, D.D., 1629, (25): : 13 - 15
  • [39] Synthesis, crystal structure, Hirshfeld surface, DFT and docking studies of 4-[(5-hydroxy-3-methyl-1-phenyl-1H-pyrazol-4-yl)(phenyl)methyl]-5-methyl-2-phenyl-1,2-dihydro-3H-pyrazol-3-one
    Rajamanickam, Ramachandran
    Sivakolunthu, Senthan
    Sampathkumar, Jayanthi
    JOURNAL OF MOLECULAR STRUCTURE, 2022, 1252
  • [40] DISTRIBUTION STUDIES OF ACTINIDES USING A TETRADENTATE EXTRACTANT, 4,4'-NONANEDIOYL-BIS(2,4-DIHYDRO-5-METHYL-2-PHENYL-3H-PYRAZOL-3-ONE)
    ENSOR, DD
    GLASGOW, DC
    SMITH, BF
    JARVINEN, GD
    JONES, MM
    SEPARATION SCIENCE AND TECHNOLOGY, 1990, 25 (13-15) : 1629 - 1639
12345