THE FREQUENCY-SPECTRUM OF THE STRUCTURE ELEMENTS OF FILLED POLY(VINYLCHLORIDE)

被引:0
|
作者
KOLUPAEV, BS [1 ]
BORDJUK, NA [1 ]
VOLOSHIN, OM [1 ]
LIPATOV, YS [1 ]
机构
[1] UKRAINIAN ACAD SCI,INST MACROMOLEC CHEM,KIEV 252160,UKRAINE
来源
JOURNAL OF POLYMER MATERIALS | 1995年 / 12卷 / 02期
关键词
FREQUENCY SPECTRUM; PVC; STRUCTURAL ELEMENT; INTERACTION POTENTIAL;
D O I
暂无
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The calculation of frequency spectrum of PVC-structure elements in filled compositions is made using the potential of interatomic interaction. If was shown that the frequency of the structure elements oscillation at the polymer-filler phase boundary exceeds the frequency of pure PVC. Determination of the force of maximum interaction between structural kinetic elements of filled PVC permitted to estimate the value of internal disruptive tension of the bonds. The satisfactory agreement was found between calculated frequency spectrum of structure elements in PVC-systems, obtained using the interaction potential and model of linear chain with side branches.
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页码:143 / 149
页数:7
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