SYNTHESIS OF MONOBUTYRYLGLYCEROL BY TRANSESTERIFICATION WITH SOLUBLE AND IMMOBILIZED LIPASES

被引：19
|
作者：
OTERO, C [1 ]
PASTOR, E [1 ]
BALLESTEROS, A [1 ]
机构：
[1] CSIC,INST CATALISIS,E-28006 MADRID,SPAIN
来源：
APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY | 1990年 / 26卷 / 01期
关键词：
Candida cylindracea and pancreatic lipases; ethyl butyrate; transesterification of; glycerol esterification; lipases immobilized on Celite and on agarose; Monobutyrin; polyethylene glycol modified-lipase;
D O I：
10.1007/BF02798391
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Transesterification between ethyl butyrate and glycerol using very different lipase preparations (native, modified, and immobilized) in a two-phase system-no extra solvent added-has been investigated. Optimal conversion was obtained with the presence of 5% water in the reaction mixture. Only monobutyrin was produced in all conditions tested. The best enzyme preparations were native Candida cylindracea lipase, Mucor miehei lipase immobilized on a phenol-formaldehyde exchange resin (Lipozyme™), and C. cylindracea lipase immobilized on Celite. © 1990 Humana Press Inc.
引用
收藏
页码：35 / 44
页数：10
相关论文
共 50 条
  • [21] Biodiesel synthesis by enzymatic transesterification of palm oil with ethanol using lipases from several sources immobilized on silica-PVA composite
    Moreira, Ana B. R.
    Perez, Victor H.
    Zanin, Gisella M.
    de Castro, Heizir F.
    ENERGY & FUELS, 2007, 21 (06) : 3689 - 3694
  • [22] INFLUENCE OF THE SUPPORT ON THE REACTION COURSE OF TRIBUTYRIN HYDROLYSIS CATALYZED BY SOLUBLE AND IMMOBILIZED LIPASES
    OTERO, C
    PASTOR, E
    FERNANDEZ, VM
    BALLESTEROS, A
    APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY, 1990, 23 (03) : 237 - 247
  • [23] IMMOBILIZED PROTEASES AND LIPASES
    KILARA, A
    PROCESS BIOCHEMISTRY, 1981, 16 (02) : 25 - +
  • [24] Immobilized lipases and their applications
    Alloue, Waze Aimee Mireille
    Aguedo, Mario
    Destain, Jacqueline
    Ghalfi, Hakim
    Blecker, Christophe
    Wathelet, Jean-Paul
    Thonart, Philippe
    BIOTECHNOLOGIE AGRONOMIE SOCIETE ET ENVIRONNEMENT, 2008, 12 (01): : 57 - 68
  • [25] Evaluation of different immobilized lipases in transesterification reactions using tributyrin: Advantages of the heterofunctional octyl agarose beads
    Hirata, Daniela B.
    Albuquerque, Tiago L.
    Rueda, Nazzoly
    Virgen-Ortiz, Jose J.
    Tacias-Pascacio, Veymar G.
    Fernandez-Lafuente, Roberto
    JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2016, 133 : 117 - 123
  • [26] ENGINEERING OF LIPASES AND PROTEASES FOR IMPROVED TRANSESTERIFICATION
    ESTELL, D
    GRAYCAR, TP
    VONBEILEN, J
    POULOSE, AJ
    PEPSIN, MJ
    ARBIDGE, MV
    JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1987, 64 (09) : 1253 - 1253
  • [27] Insight into the synthesis of isosorbide diester plasticizer using immobilized lipases
    Cui, Caixia
    Zhang, Zhe
    Zeng, Qingqian
    Chen, Biqiang
    RSC ADVANCES, 2016, 6 (110) : 108180 - 108186
  • [28] Performance of different immobilized lipases in palm oil biodiesel synthesis
    Silva, Grazielle dos Santos
    Inoue, Dayana Yuri
    Dors, Gisanara
    Furigo Junior, Agenor
    de Castro, Heizir Ferreira
    ACTA SCIENTIARUM-TECHNOLOGY, 2011, 33 (02) : 197 - 203
  • [29] Efficient immobilized lipases for biodiesel synthesis from waste lipids
    Rivera, Ivanna
    Carlos Mateos, Juan
    Sandoval, Georgina
    JOURNAL OF BIOTECHNOLOGY, 2007, 131 (02) : S265 - S265
  • [30] SYNTHESIS OF STEREOSPECIFIC ESTERS AND RESOLUTION OF RACEMIC ALCOHOLS WITH IMMOBILIZED LIPASES
    SAGIROGLU, A
    TELEFONCU, A
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1993, 32 (01): : 85 - 87
12345