PHOSPHORESCENCE LIFETIME-BASED SENSING OF SO2 IN THE GAS-PHASE

被引:11
|
作者
PAPKOVSKY, DB [1 ]
DESYATERIK, IV [1 ]
PONOMAREV, GV [1 ]
KUROCHKIN, IN [1 ]
KORPELA, T [1 ]
机构
[1] UNIV TURKU,FINNISH RUSSIAN JOINT BIOTECHNOL LAB,SF-20520 TURKU,FINLAND
关键词
SULFUR DIOXIDE; GAS SENSOR; FIBEROPTIC; LUMINESCENCE; PHOSPHORESCENCE; LIFETIME-BASED SENSOR; PORPHYRINS; LANGMUIR-BLODGETT FILMS;
D O I
10.1080/00032719508000022
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Two different types of solid-state coatings based on the phosphorescent metalloporphyrins - polymer film compositions or Langmuir-Blodgett films - were studied comparatively with respect to their application to sensing of SO2. While the polymer films were only slightly sensitive to SO2, LB-coatings appeared to be highly suitable for analyzing SO2 in air in the range 0.01 - 2 % (v/v). Performance characteristics of the new phosphorescence lifetime-based sensor for SO2 were studied. Interferences by a number important species on sensing of SO2 in gas phase were studied.
引用
收藏
页码:2027 / 2040
页数:14
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