PREPARATION OF VINYLPHOSPHINES BY MEANS OF FREE-RADICAL ADDITION OF DIPHENYLPHOSPHINE TO ALKYNES AND ALLENES

被引：50
|
作者：
MITCHELL, TN
HEESCHE, K
机构：
[1] Fachbereich Chemie, Universität Dortmund, W-4600 Dortmund 50
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 409卷 / 1-2期
关键词：
D O I：
10.1016/0022-328X(91)86141-C
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Diphenylphosphine adds readily to alkynes and allenes under free radical conditions. Alkynes normally give E-vinylphosphines as the primary (kinetic) product, but Z-vinylphosphines are the main products isolated. Allenes generally give complex product mixtures in which the predominant components are vinyl phosphines formed via addition of the Ph2P. radical to the central carbon atom of the allene fragment.
引用
收藏
页码：163 / 170
页数：8
相关论文
共 50 条
12345