AN EXAFS STUDY OF GRIGNARD COMPOUNDS IN SOLUTION

被引:7
|
作者
ERTEL, TS
BERTAGNOLLI, H
机构
[1] Institut für Physikalische Chemie, Universität Stuttgart Pfaffenwaldring 55
关键词
D O I
10.1016/S0277-5387(00)88254-6
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The results of an EXAFS study of the Grignard compounds methyl, ethyl and phenyl magnesium bromide in diethyl ether and vinyl magnesium bromide in tetrahydrofuran are presented in this paper. The degree of molecular association and the local structure around the central magnesium atoms are deduced from the determined distances and coordination numbers.
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页码:2175 / 2184
页数:10
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