SUPERLONG-RANGE INTERACTIONS OF COLLOIDS

被引:6
|
作者
YOSHINO, S
机构
[1] Department of Physics, School of Science, Nagoya University, Nagoya
关键词
COLLOID; INTERACTION; SUPERLONG-RANGE INTERACTION; DYNAMIC ELECTRICAL MULTIPOLE MODEL; DLVO THEORY;
D O I
10.1002/pi.4990300419
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Colloid particles have superlong-range attractive and repulsive forces. The distance between the secondary minimum of the potential energy of the interaction and the surface of the colloid is of the order of several mum and several tens of mum. These interactions clearly appear in the distribution of order-solution phase coexistence, in gathering particles to the ordered phase and in spontaneous pair formation. A new 'Dynamic electrical multipole model and resonance effect' is given. From this model, it is predicted that pairs will form in a shear field even in highly concentrated salt solution. Pair formation was observed after 24 hours as predicted.
引用
收藏
页码:541 / 546
页数:6
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