The 1:1 charge-transfer complex dibenzotetrathiafulvalene-pyromellitic dianhydride (DBTTF-PMDA)

被引：3

作者：

Payne, Margaret E. ^{[1
]}

Goetz, Katelyn P. ^{[1
]}

Day, Cynthia S. ^{[2
]}

Jurchescu, Oana D. ^{[1
]}

机构：

[1] Wake Forest Univ, Dept Phys, Winston Salem, NC 27109 USA

[2] Wake Forest Univ, Dept Chem, Winston Salem, NC 27109 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2014年 / 70卷

基金：

美国国家科学基金会;

关键词：

D O I：

10.1107/S1600536814013324

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title charge-transfer (CT) complex, C10H2O6 center dot C14H8S4, composed of donor dibenzotetrathiafulvalene (DBTTF) and acceptor pyromellitic dianhydride (PMDA), forms a mixed stacking pattern along the [110] direction. The constituent molecules occupy crystallographic inversion centers. They are nearly parallel and lie ca. 3.41 angstrom from each other. The crystals exhibit a high degree of donor/acceptor overlap [88.20 (4)%] in the long direction of the DBTTF and PMDA molecules as compared with 51.27 (5)% in the shortest direction of the molecules.

引用

页码：O844 / +

页数：9

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